TY  - BOOK
AU  - Ross,Gaylon S.
AU  - Enagonio,Delmo
AU  - Hewitt,Clifford A.
AU  - Glasgow,Augustus R.
TI  - Preparation of High Purity Trimethylborane1
PY  - 1962///
PB  - [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology, 
KW  - Text
KW  - local
N1  - /pmc/articles/PMC5327742
N2  - The preparation of high-purity trimethylborane is described. Impurities were removed by fractionation of the ammonia adduct, NH(3):B(CH3)(3). Mass spectrometric analyses were used during the fractionation to determine these impurities. After purification of the B (CH(3))(3) in the form of its ammonia adduct, high-purity hydrogen chloride was used to regenerate the B(CH(3))(3). This reaction and the subsequent distillation were carried out in a stainless steel system. Storage as a gas in stainless steel cylinders, rather than as a solid addition complex in glass vessels, eliminated the possibility of recontamination on regeneration. The purity of B(CH(3))(3) was determined cryoscopically to be 99.9 mole percent
UR  - http://dx.doi.org/10.6028/jres.066A.006
ER  -