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Conductometric Determination of Sulfhydryl Groups in Swollen Polycaprolactam Fibers Having Disulfide and Alkylene Sulfide Crosslinks

By: Contributor(s): Publication details: [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology, 1962.Subject(s): Genre/Form: Online resources: Summary: A simple conductometric titration method is discussed for the determination of sulfhydryl groups in nonionic polymer networks, such as disulfide and alkylene sulfide crosslinked polycaprolactam fibers. The diffusion of the titrant into the crosslinked polymer is accomplished by swelling the network structure, thereby eliminating the necessity of destroying the crosslinks and/or breaking the polymer chains.
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/pmc/articles/PMC5315335/

A simple conductometric titration method is discussed for the determination of sulfhydryl groups in nonionic polymer networks, such as disulfide and alkylene sulfide crosslinked polycaprolactam fibers. The diffusion of the titrant into the crosslinked polymer is accomplished by swelling the network structure, thereby eliminating the necessity of destroying the crosslinks and/or breaking the polymer chains.

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The Journal of Research of the National Bureau of Standards Section A is a publication of the U.S. Government. The papers are in the public domain and are not subject to copyright in the United States. Articles from J Res may contain photographs or illustrations copyrighted by other commercial organizations or individuals that may not be used without obtaining prior approval from the holder of the copyright.

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