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Reaction of Several Aminopyrimidines With Formaldehyde

By: Publication details: [Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology, 1962.Subject(s): Genre/Form: Online resources: Summary: Formaldehyde has been shown to react with 2-aminopyrimidine (II) and 2-(methylamino) pyrimidine (V) at room temperature to give the corresponding methylol derivatives or the corresponding methylenebis(aminopyrimidines). The reaction of formaldehyde with 2-amino-4,6-dichloro-5-methylpyrimidine (VII) and also its failure to react with 2-(dimethylamino)pyrimidine (IX) are cited as evidence that the pyrimidine ring is not involved in the reaction.
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/pmc/articles/PMC5327744/

Formaldehyde has been shown to react with 2-aminopyrimidine (II) and 2-(methylamino) pyrimidine (V) at room temperature to give the corresponding methylol derivatives or the corresponding methylenebis(aminopyrimidines). The reaction of formaldehyde with 2-amino-4,6-dichloro-5-methylpyrimidine (VII) and also its failure to react with 2-(dimethylamino)pyrimidine (IX) are cited as evidence that the pyrimidine ring is not involved in the reaction.

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The Journal of Research of the National Bureau of Standards Section A is a publication of the U.S. Government. The papers are in the public domain and are not subject to copyright in the United States. Articles from J Res may contain photographs or illustrations copyrighted by other commercial organizations or individuals that may not be used without obtaining prior approval from the holder of the copyright.

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