[Gaithersburg, MD] : U.S. Dept. of Commerce, National Institute of Standards and Technology,
Date of publication, distribution, etc.
1962.
500 ## - GENERAL NOTE
General note
/pmc/articles/PMC5327746/
520 ## - SUMMARY, ETC.
Summary, etc.
The introduction of alkylene sulfide crosslinks into oriented nylon-6 (polycaprolactam) homofiber is described. The resulting structural modifications are found to produce crimping and coiling in the dry and wet states of the fiber resembling the situation in wool. In a previous paper a similar phenomenon was reported for a disulfide crosslinked nylon-6 homofiber. The macroscopic deformations exhibited by the alkylene sulfide crosslinked fibers differ in. at least three respects from the disulfide crosslinked samples: (1) the crimp frequency is much higher and the crimp amplitude smaller, (2) in addition to crimping some helical coiling takes place even when the fiber is in the unswollen state, and (3) the extent of crimping and coiling is not decreased by gradual air-oxidation of some of the reactive groups. An explanation for this crimping and coiling previously advanced is corroborated by additional evidence provided by chemical analyses, and X-ray diffraction, birefringence, and swelling data.
540 ## - TERMS GOVERNING USE AND REPRODUCTION NOTE
Terms governing use and reproduction
540 ## - TERMS GOVERNING USE AND REPRODUCTION NOTE
Terms governing use and reproduction
https://creativecommons.org/publicdomain/zero/1.0/The Journal of Research of the National Bureau of Standards Section A is a publication of the U.S. Government. The papers are in the public domain and are not subject to copyright in the United States. Articles from J Res may contain photographs or illustrations copyrighted by other commercial organizations or individuals that may not be used without obtaining prior approval from the holder of the copyright.
546 ## - LANGUAGE NOTE
Language note
en
690 ## - LOCAL SUBJECT ADDED ENTRY--TOPICAL TERM (OCLC, RLIN)
